Interaction of ethyl alcohol vapor with sulfuric acid solutions

Abstract

We investigated the uptake of ethyl alcohol (ethanol) vapor by sulfuric acid solutions over the range ~40 to ~80 wt % H2SO4 and temperatures of 193-273 K. Laboratory studies used a fast flow-tube reactor coupled to an electron-impact ionization mass spectrometer for detection of ethanol and reaction products. The uptake coefficients (γ) were measured and found to vary from 0.019 to 0.072, depending upon the acid composition and temperature. At concentrations greater than ~70 wt % and in dilute solutions colder than 220 K, the values approached ~0.07. We also determined the effective solubility constant of ethanol in ~40 wt % H2SO4 in the temperature range 203-223 K. The potential implications to the budget of ethanol in the global troposphere are briefly discussed.