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Experimental and coupled-channels investigation of the radiative properties of the N2 ć4 X¹Ε+u-X¹Ε+g band system

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dc.contributor.author Liu, Xianming
dc.contributor.author Shemansky, Donald E.
dc.contributor.author Malone, Charles P.
dc.contributor.author Johnson, Paul V.
dc.contributor.author Ajello, Joseph M.
dc.contributor.author Kanik, Isik
dc.contributor.author Heays, Alan N.
dc.contributor.author Lewis, Brenton R.
dc.contributor.author Gibson, Stephen T.
dc.contributor.author Stark, Glenn
dc.date.accessioned 2008-09-04T17:55:29Z
dc.date.available 2008-09-04T17:55:29Z
dc.date.issued 2008-02-14
dc.identifier.citation JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 113, A02304, doi:10.1029/2007JA012787, 2008 en_US
dc.identifier.clearanceno 07-0815
dc.identifier.uri http://hdl.handle.net/2014/40943
dc.description.abstract The emission properties of the N2 ć4¹ 1Ε+u - X¹Ε+g band system have been investigated in a joint experimental and coupled-channels theoretical study. Relative intensities of the ć4¹1Ε+u(0)- X¹Ε+g(vi) transitions, measured via electron-impact-induced emission spectroscopy, are combined with a coupled-channel Schrodinger equation (CSE) model of the N2 molecule, enabling determination of the diabatic electronic transition moment for the c04 1Su + - X¹Ε+g system as a function of internuclear distance. The CSE rotational transition probabilities are further verified by comparison with a high-resolution experimental spectrum. Spontaneous transition probabilities of the ć4¹ 1Ε+u- X¹Ε+g band system, required for modeling atmospheric emission, can now be calculated reliably. en_US
dc.description.sponsorship NASA/JPL en_US
dc.language.iso en_US en_US
dc.publisher American Geophysical Union en_US
dc.subject Schrödinger equation (CSE) en_US
dc.subject internuclear distance en_US
dc.subject modeling atmospheric emissions en_US
dc.title Experimental and coupled-channels investigation of the radiative properties of the N2 ć4 X¹Ε+u-X¹Ε+g band system en_US
dc.type Preprint en_US


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